Waterborne UV-Curable Coatings for Industrial Market Segments

by Raymond Stewart, CAS-NAFTA applications development, Covestro LLC

Abstract

Ultraviolet (UV) light-cured waterborne polyurethane dispersions (PUDs) are versatile in many industrial market segments. Today, there are ever-increasing customer requests for film properties specific to more than one market. There is no general solution: each customer has his/her own list of coating requirements. To meet customer expectations, the formulator needs a general approach for formulation development. In this article, we discuss a formulating strategy for using blends of UV-curable PUDs and non-UV-curable PUDs to attain desired film properties.

Introduction

Ultraviolet (UV) light-cured waterborne polyurethane dispersions (PUDs) have demonstrated their versatility in many industrial market segments.1 However, the increasing demands of the marketplace challenge the formulator to develop timely coatings solutions. The emphasis is on timely – often, the formulator is expected to use limited resources to formulate coatings for new applications from his existing product portfolio. We will examine a not-so-new approach and tool for the formulator to use. We also will include some test examples to illustrate the power of the tool – design of experiments (DOE).

Usually there is a groan at this point, and those of you who feel the pressure of new product development will gasp and politely change the discussion to ways that you can avoid a horrendous number of experiments. I suggest those of you who are wedded to OFAT (Stat-Ease, Inc. terminology for one factor at a time) consider that (a) principles of DOE are firmly established and (b) software advances have produced strong analytical tools to analyze the results that you’ve worked so hard to obtain. Several software manufacturers will be happy to teach you either in person or online.2 I’ll concentrate on a real-life example that we recently encountered in the BMS laboratories in Pittsburgh, Pennsylvania.

Let me close this introductory section by stating that I am not a statistician. I am a paint formulator who has been privileged to work at several paint companies with first-rate formulating chemists. You are not putting your technical training aside when you use DOE software. Quite the contrary – you’ll find that you can use your experience to develop more robust formulations than the ones you’ve been tweaking over the months and years.

Relevance of DOE to paint formulation development

We regularly examine our portfolio of waterborne products for new applications in new markets. We do the usual tests that you’d do for classifying PUDs according to their coatings properties – hardness, chemical resistance, flexibility, impact resistance and durability, to name a few. These performance properties are important and often are specified by the customer. A recent need to characterize some of our PUDs provided us with the opportunity to set up a DOE for such an evaluation.

TABLE 1. Properties of WB PUDs

We had done some preliminary work with several of our PUDs for general property characterizations. I’ve listed the ones that we’ll be discussing in Table 1. The properties are listed in our technical literature. We had reason to ask if there were additional simple characterizations relevant for formulation development.

We did this set of experiments in two parts. We began with a four-component design comprised of A, B, C and D. We used a commercially available software package and confined our study to the interactions of A, B, C and D as a mixture of paint components in a mixture design.2 After some internal discussion, we settled on a Simplex Centroid design augmented with axial points with two replicates for the whole design. This resulted in 38 formulations, which we prepared according to internal formulation guidelines. We were interested in the interactions of the waterborne UV-curable PUDs with waterborne PUDs that did not UV-cure nor would further cross-link after application. We have included key application and cure data in the appendix. All PUDs are commercially available.

After we had completed our initial work, we substituted PUD D with another PUD E. We used the same experimental design for a second series with the same guide formulation and application/cure parameters.

In the analysis of the experimental results, we used output from a Fischerscope 100HC Nanoindenter.3 Although the Martens Hardness, HM (N/mm2), is an often-cited result, we included hmaxμ (μm), maximum indentation depth of the indenter at maximum test load and elastic modulus, EIT/(1-vs^2) (GPA).4 Both of these latter terms are standard output from this instrument.3,4

We will focus on the general trends that we see from the indentation experiments. We found the option of “contour plots” provided within the DOE software to be helpful. Briefly, the concentrations of each PUD (A, B, C, D and E) are 100% of each component at the three vertices. The midpoint of each side of the triangle is equal to 0% for each component at the opposite vertex. We intentionally wanted to see the interaction of both waterborne UV-curable with the non-UV-curing components; therefore, each contour plot contained one or both UV-curable resins.

Martens Hardness HM

Figure 1. ABC Contour Plots of HM with D= 0 and E=0

Initially, we consider the case of formulation ABC in which either D or E is held constant at zero (Figure 1). The contour plot for ABC with D=0 differs slightly from ABC with E=0, due to the model generated from setting D=0 versus E=0 produced by the software based on the input mixtures.

The ranges of HM are color coded and range from 0 to >125 N/mm2. The contour plots were constructed based on the model heretofore described. Note that within the dark green region, the model predicts that one can obtain a Martens Hardness ranging from 80 to 100 H/mm2; moreover, when E is substituted for D in the same guide formulations, the model predicts the same Martens Hardness range in the same region of the model. This is an expected result and also confirms the high predictability of the DOE model for both cases.4

Henceforth, we’ll refer to contour plots ABC with C=0 or D=0 for comparisons.

Figure 2. ABD and ABE Contour Plot of HM with C=0

If we now consider the case of formulations ABD and ABE in which C=0 (Figure 2), we see qualitatively the same trends as for the ABC formulation. These HM results indicate little or no change when PUDs C, D and E are interchanged as the third component in AB formulations.

Figure 3. ACD and ACE Contour Plots of HM with B=0

If we then consider the case in which one of the UV-curable waterborne resins, B, is set to zero, we see a dramatic shift for ACD formulations. It is not possible to reach Martens Hardness values greater than 50 N/mm2; substituting E for D produces even softer films within the design space of ACE formulations (Figure 3).

Figure 4. BCD and BCE Contour Plots of HM with A=0

If we now substitute UV-curable PUD B for A, we have the results in Figure 4.

At this point, we have accumulated considerable knowledge about the interactions of waterborne UV-curable resins A and B with non-UV-curable resins C, D and E; moreover, the change from AB mixtures to ones containing only A or B produce either lower ranges of HM values or more narrow ranges of formulations for maximum HM values.

We conclude at this point that removal of either A or B from the formulation will make it more challenging to create formulations with high levels of hardness.

These contour plots are based on a very high correlation of the data with the model.5 Consequently, one can predict with a high degree of probability the Martens Hardness results of mixtures within the design space that were not part of the original test series. Moreover, formulations ABC, ABD and ABE are more robust than ACD, ACE, BCD and BCE. One has a wider formulating window with ABC, ABD and ABE to attain desired hardness than with ACD, ACE, BCD and BCE.

There are two other outputs from the nanoindenter that we’ll consider in the same fashion – hmaxμ, maximum penetration beneath specimen’s surface in mm (nm) at maximum test load and EIT/(1-vs^2), elastic modulus, an object or substance’s tendency to be deformed elastically (i.e., non-permanently) when a force is applied to it.4

Maximum penetration at maximum test load hmaxμ

If we compare the hmaxµ plots (Figures 5, 6 and 7), we see the same trend: ABC, ABD and ABE provide a wider range of formulations for desired hmaxμ values than ACD, ACE, BCD and BCE (Figure 8). This trend is opposite to that of HM because hmaxμ is a measure of the depth of penetration; hmaxμ decreases as the formulations are enriched in A or B and increases as formulations are enriched in C, D or E. The higher glass transition temperatures of A and B compared to C, D and E may explain this trend.

Figure 5. ABC Contour Plots of hmaxμ with D= 0 and E=0
Figure 6. ABD and ABE Contour Plot of hmaxμ with C=0
Figure 7. ACD and ACE Contour Plots of hmaxμ with B=0
Figure 8. ACD and ACE hmaxμ Contour Plots with A=0

Elastic modulus EIT/(1-vs^2)

Lastly, we consider EIT/(1-vs^2), elastic modulus. Contour plots ABC, ABD and ABE have the same general appearance as the HM plots of ABC, ABD and ABE (Figures 9 and 10 and Figures 1 and 2). Likewise, contour plots ACD, ACE, BCD and BCE have the same general appearance as HM contour plots of ACD, ACE, BCD and BCE (Figures 11 and 12 and Figures 3 and 4). These data show elastic modulus to be trending the same as HM in this series. This is intuitively obvious if one recalls that elastic modulus increases with increasing stiffness of the film due, in part, to the higher glass transition temperatures of UV-curable PUDs A and B.6

Figure 9. ABC Contour Plots of EIT/(1-vs^2) with D=0 and E=0
Figure 10. ABD and ABE Contour Plots of EIT/(1-vs^2) with C=0
Figure 11. ACD and ACE Contour Plots of EIT/(1-vs^2) with B=0
Figure 12. BCD and BCE Contour Plots of EIT/(1-vs^2) with A=0

Conclusions

  1. Blends of waterborne UV-curable PUDs and waterborne non-UV-curable PUDs provide additional formulating aids to meet customer coating requirements.
  2. DOE is a powerful tool for the formulator to assess interaction of binder components in paint formulations.
  3. Analysis of DOE results can provide insights into how film properties vary within a design space, thereby allowing one to predict film properties for formulations not actually tested.
  4. DOE requires both a sound design and analysis of results to enhance the skill of the formulator.

References

  1. “UV Curable Resins Market by Application (Coatings, Inks, Adhesives, & Others), End-User Industry (Graphic Arts, Industrial Coatings, Electronics & Others) & Geography – Trends & Forecasts to 2018,” http://www.marketsandmarkets.com/Market-Reports/uv-curable-resins-market-1324.html.
  2. The author used Minitab® 16 for the design and analysis of the results reported herein.
  3. Fischerscope® H100C Microhardness Measurement System with WIN-HCU® Software; Measurement of the Martens Hardness According to DIN 14577. Fischer Technology, Inc., 750 Marshall Phelps Road, Windsor, CT 06095 USA.
  4. Anthony C. Fischer-Cripps. Nanoindentation, Third Edition, Spring, pp. 14-15, 184-189.
  5. Regression Analysis from Minitab 16 (Mixture Design, Analysis of Mixture Design Results, Regression) *Standard error; **Predicted Sum of Squares; ***R-Sq=R2; ****R2pred; *****R2adj
  6. F.N. Jones et al., “Methods for Studying the Mechanical and Tribological Properties of Hard and Soft Coatings with a Nano-Indenter,” JCT Research, Vol. 1, No. 2, April 2004, pp. 117-125; www.coatingstech.org

Application and cure parameters

  • 10 mil (wet) drawdowns were made onto Baybond® T85 plastic (PC/ABS) panels (precleaned with a solvent solution of Isopropyl Alcohol and VMP Naphtha 50/50 by weight).
  • Drawdowns were air flashed 30 minutes; baked at 60 deg C for 10 min and then UV-cured.
  • UV-cure parameters: Mercury lights at 100% intensity, belt speed 30 feet/minute, lamps 2.25 inches from glass panels.
  • Measurements made with 30ft/min POWER PUCK
  • UAV 0.880 J/CMUVA 1.850 W/CM
  • UVB 0.616 J/CMUVB 1.614 W/CM
  • UVC 0.105 J/CMUVC .239 W/CM
  • UVV 0.529 J/CMUVV 1.267 W/CM
  • Microhardness testing was performed after ~1 week aging of cured films.

Acknowledgements

  1. Covestro LLC, formerly Bayer MaterialScience LLC, for permission to submit this paper.
  2. Chuck Gambino and Chris Mebane for the laboratory test results.

Raymond Stewart received his Ph.D. in chemistry from the University of Illinois Urbana-Champaign. Over the course of 40 years, Stewart has worked for PPG, Sherwin Williams, Akzo Nobel and Bondo Corporation in a variety of technical management positions. Currently, he is a senior scientist at Covestro LLC (formerly Bayer MaterialScience LLC) where he is completing his 12th year of employment in product development for Coatings Adhesives and Specialties. Contact Raymond Stewart at [email protected].

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